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3,4-二甲基(2,3-B)并噻吩-2,5-二羧酸
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3,4-二甲基(2,3-B)并噻吩-2,5-二羧酸
3,4-Dimethylthieno(2,3-b)thiophene-2,5-dicarboxylic acid
CAS:175202-55-8 分子式:C20H10N4S 分子量:338.3852
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产品名称:3,​4-​Dimethylthieno[2,​3-​b]​thiophene-​2,​5-​dicarboxylic acid
其他名称:H2DMTDC
CAS:175202-55-8
结构信息
分子式 C10H8O4S2 分子量 256.29812
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:IFMC-​27 / IFMC-​28 [r1] ; Zr(DMTDC)[r2] ; NENU‐512 [r3] ; Ln(DMTDC)​1.5(H2O)​2 (Ln = Eu , Tb , Gd , Dy , Er) [r5]; UIO-66(Ce)-DMTDC [r6]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Yang, G.; Lang, Z.; Zang, H.; Lan, Y.; He, W.; Zhao, X.; Yan, L.; Wang, X.; Su, Z.; Chem. Commun. 2013, 49(11), 1088-1090, DOI: 10.1039/c2cc36894c ;
Control of interpenetration in S-containing metal–organic frameworks for selective separation of transition metal ions
2) Wang, K.; Huang, H.; Xue, W.; Liu, D.; Zhao, X.; Xiao, Y.; Li, Z.; Yang, Q.; Wang, L.; Zhong, C.; CrystEngComm 2015, 17(19), 3586-3590, DOI: 10.1039/C5CE00269A ; An ultrastable Zr metal-​organic framework with a thiophene-​type ligand containing methyl groups
3) He, W.; Yang, G.; Tang, Y.; Li, S.; Zhang, S.; Su, Z.; Lan, Y.; Chem.- Eur. J. 2015, 21(27), 9784-9789, DOI: 10.1002/chem.201500815 ; Phenyl Groups Result in the Highest Benzene Storage and Most Efficient Desulfurization in a Series of Isostructural Metal-​Organic Frameworks
4) Qin, J.; Du, D.; Li, M.; Lian, X.; Dong, L.; Bosch, M.; Su, Z.; Zhang, Q.; Li, S.; Lan, Y.; Yuan, S.; Zhou, H.; J. Am. Chem. Soc. 2016, 138, 16, 5299-5307, DOI: 10.1021/jacs.6b01093 ; 10.1021/jacs.6b01093 ; Derivation and Decoration of Nets with Trigonal-​Prismatic Nodes: A Unique Route to Reticular Synthesis of Metal-​Organic Frameworks5) Wang, S.; Cao, T.; Yan, H.; Li, Y.; Lu, J.; Ma, R.; Li, D.; Dou, J.; Bai, J.; Inorg. Chem. 2016, 55(11), 5139-5151, DOI: 10.1021/acs.inorgchem.5b02801 ; Functionalization of Microporous Lanthanide-​Based Metal-​Organic Frameworks by Dicarboxylate Ligands with Methyl-​Substituted Thieno[2,​3-​b]​thiophene Groups: Sensing Activities and Magnetic Properties6) Dalapati, R.; Sakthivel, B.; Ghosalya, M.; Dhakshinamoorthy, A.; Biswas, S.; CrystEngComm 2017, 19(39), 5915-5925, DOI: 10.1039/C7CE01053B ; A cerium-​based metal-​organic framework having inherent oxidase-​like activity applicable for colorimetric sensing of biothiols and aerobic oxidation of thiols

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3,4-二甲基(2,3-B)并噻吩-2,5-二羧酸
3,4-二甲基(2,3-B)并噻吩-2,5-二羧酸