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1,1'-(苯-1,4-二基二甲基)-双(3,5-二甲基-1H-吡唑)
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1,1'-(苯-1,4-二基二甲基)-双(3,5-二甲基-1H-吡唑)
1,1'-(Benzene-1,4-Diyldimethylene)-Bis(3,5-Dimethyl-1H-Pyrazole)
CAS:172606-22-3 分子式:C18H22N4 分子量:294.39408
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产品名称:1,1'-(Benzene-1,4-Diyldimethylene)-Bis(3,5-Dimethyl-1H-Pyrazole)
其他名称:1,1'-(苯-1,4-二基二甲基)-双(3,5-二甲基-1H-吡唑);bdb;1,​4-​bis((3,​5-​dimethyl-​1H-​pyrazol-​1-​yl)​methyl)​benzene
CAS:172606-22-3
结构信息
分子式  C18H22N4 分子量  294.39408
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Ag(μ-​bpb)​2]​ [r4]; [Cu(μ-​bpb)​2]​(PF6) [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Hartshorn, Chris M.; Steel, Peter J.; Australian J. Chem. 1995, 48(9), 1587-1599, DOI: 10.1071/CH9951587 ; Poly(pyrazol-​1-​ylmethyl)​benzenes: new multidentate ligands
2) Wang, Xin-Yu; Liu, Shu-Qing; Zhang, Chun-Yan; Song, Ge; Bai, Feng-Ying; Xing, Yong-Heng; Shi, Zhan; Polyhedron 2012, 47(1), 151-164, DOI: 10.1016/j.poly.2012.08.016 ; Synthesis, structural, and biological evaluation of the arene-​linked pyrazolyl methane ligands and their d9​/d10 metal complexes
3) Budhai, Asheena; Omondi, Bernard; Ojwach, Stephen O.; Obuah, Collins; Osei-Twum, Emmanuel Y.; Darkwa, James; Catalysis Sci. Tech. 2013, 3(12), 3130-3135, DOI: 10.1039/c3cy00334e ; Tandem ethylene oligomerisation and Friedel-​Crafts alkylation of toluene catalysed by bis-​(3,​5-​dimethylpyrazol-​1-​ylmethyl)​benzene nickel(ii) complexes and ethylaluminium dichloride
4) Azizzadeh, Sara; Nobakht, Valiollah; Carlucci, Lucia; Proserpio, Davide M.; Polyhedron 2017, 130, 58-66, DOI: 10.1016/j.poly.2017.03.048 ; Self-​assembly of three cationic silver(I) coordination networks with flexible bis(pyrazolyl)​-​based linkers
5) Baladi, Elham; Nobakht, Valiollah; Tarassoli, Abbas; Proserpio, Davide M.; Carlucci, Lucia; Cryst. Growth & Des. 2018, 18(11), 7207-7218, DOI: 10.1021/acs.cgd.8b01446 ; Three Cationic, Nonporous CuI-​Coordination Polymers: Structural Investigation and Vapor Iodine Capture

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1,1'-(苯-1,4-二基二甲基)-双(3,5-二甲基-1H-吡唑)
1,1'-(苯-1,4-二基二甲基)-双(3,5-二甲基-1H-吡唑)