1,2,4,5-四吡啶基苯
4,4',4'',4'''-(1,2,4,5-benzenetetrayl)tetrakis-Pyridine
CAS:170165-81-8
分子式:C26H18N4
分子量:386.44792
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产品名称： 4,4',4'',4'''-(1,2,4,5-benzenetetrayl)tetrakis- Pyridine
其他名称： 4，4'，4''，4'''-（1,2,4,5-苯四基）四吡啶；bztpy; TPB
CAS： 170165-81-8
其他名称： 4，4'，4''，4'''-（1,2,4,5-苯四基）四吡啶；bztpy; TPB
CAS： 170165-81-8
结构信息
| 分子式 | C26H18N4 | 分子量 | 386.44792 | ||
| 性状照片 |  |
||||
性质说明
1) 170165-81-8 溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料，如：SNNU-45 [r3]; SCU‐19 [r4]; CPM-322 [r5]
表征图谱
参考文献
1) Fujita, M.; Oka, Hi.; Ogura, K. Tetrahedron Lett. 1995, 36(29), 5247-5250, DOI:10.1016/0040-4039(95)00983-J ; Palladium(0)/LiCl promoted cross-coupling reaction of (4-pyridyl)stannanes and aromatic bromides: Easy access to poly(4-pyridyl)-substituted aromatics
2) Zhang, J.; Wu, T.; Feng, P.; Bu, X. Chem. Mater. 2008, 20, 5457-5459, DOI:10.1021/cm801385m ; In Situ Synthesis of Tetradentate Dye for Construction of Three-Dimensional Homochiral Phosphor
3) Li, Y.; Wang, Y.; Xue, Y.; Li, H.; Zhai, Q.; Li, S.; Jiang, Y.; Hu, M.; Bu, X.; Angew. Chem., Int. Ed. 2019, 58(38), 13590-13595, DOI: 10.1002/anie.201908378 ; Ultramicroporous Building Units as a Path to Bi‐microporous Metal–Organic Frameworks with High Acetylene Storage and Separation Performance
4) Zhang, H.; Liu, W.; Li, A.; Zhang, D.; Li, X.; Zhai, F.; Chen, L.; Chen, L.; Wang, Y.; Wang, S.; Angew. Chem., Int. Ed. 2019, 58(45), 16110-16114, DOI: 10.1002/anie.201909718 ; Three Mechanisms in One Material: Uranium Capture by a Polyoxometalate‐Organic Framework through Combined Complexation, Chemical Reduction, and Photocatalytic Reduction
5) Nguyen, E.; Zhao, X.; Ta, D.; Nguyen, P.; Bu, X.; Cryst. Growth Des. 2015, 15(12), 5939-5944, DOI:10.1021/acs.cgd.5b01412 ; Comparative Study of In Situ and Presynthesized X-Pillar Ligand in Self-Assembly of Homochiral Porous Frameworks
| 170165-81-8-CS014001-HPLC.pdf | 下载 |
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