四(4-硼酸基苯基)甲烷
Tetra[4-(dihydroxyboryl)phenyl]methane
CAS:153035-55-3
分子式:C25H24B4O8
分子量:495.69726
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产品名称：tetra(4-dihydroxyborylphenyl)methane
其他名称：
CAS：153035-55-3
其他名称：
CAS：153035-55-3
结构信息
| 分子式 | C25H24B4O8 | 分子量 | 495.69726 | ||
| 性状照片 |  |
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性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料：COF-102 [r1]; PAF-111/112/113 [r3]; PPBI-1/2 [r4]; MCOF-1 [r5]
表征图谱
参考文献
1) Schmid, R.; Tafipolsky, M.; J. Am. Chem. Soc. 2008, 130(38), 12600-12601, DOI: 10.1021/ja804734g ; An Accurate Force Field Model for the Strain Energy Analysis of the Covalent Organic Framework COF-102
2) Evans, A.; Castano, I.; Brumberg, A.; Parent, L.; Corcos, A.; Li, R.; Flanders, N.; Gosztola, D.; Gianneschi, N.; Schaller, R.; Dichtel, W.; J. Am. Chem. Soc. 2019, 141(50), 19728-19735, DOI:10.1021/jacs.9b08815 ; Emissive Single-Crystalline Boroxine-Linked Colloidal Covalent Organic Frameworks
3) Zhang, L.; Sun, J.; Sun, F.; Chen, P.; Liu, J.; Zhu, G.; Chem.-Eur. J. 2019, 25(15), 3903-3908, DOI: 10.1002/chem.201805713 ; Facile Synthesis of Ultrastable Porous Aromatic Frameworks by Suzuki–Miyaura Coupling Reaction for Adsorption Removal of Organic Dyes
4) Zhang, X.; Bian, N.; Mao, L.; Chen, Q.; Fang, .; Qi, A.; Han, B.; Macromol. Chem. Phys. 2012, 213(15), 1575-1581, DOI: 10.1002/macp.201200074 ; Porous Polybenzimidazoles via Template‐Free Suzuki Coupling Polymerization: Preparation, Porosity, and Heterogeneous Catalytic Activity in Knoevenagel Condensation Reactions
5) Ma, H.; Ren, H.; Meng, S.; Yan, Z.; Zhao, H.; Sun, F.; Zhu, G.; Chem. Commun. 2013,49, 9773-9775, DOI: 10.1039/C3CC45217D ; A 3D microporous covalent organic framework with exceedingly high C3H8/CH4 and C2 hydrocarbon/CH4 selectivity
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