2,5-Bis(allyloxy)terephthalic acid
CAS:149590-60-3
分子式:C14H14O6
分子量:278.25736
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产品名称：2,5-Di(allyloxy)terephthalic acid
其他名称：H2(BA-BDC);1,4-Benzenedicarboxylic acid, 2,5-bis(2-propenyloxy)- ; 2,5-Bis(2-propen-1-yloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)terephthalic acid
CAS：149590-60-3
3) Henke, Sebastian; Schneemann, Andreas; Wuetscher, Annika; Fischer, Roland A.; J. Am. Chem. Soc. 2012, 134(22), 9464-9474, DOI: 10.1021/ja302991b ; Directing the Breathing Behavior of Pillared-Layered Metal-Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents
4) Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A.; Ploskonka, Ann M.; DeCoste, Jared B.; Cohen, Seth M.; J. Am. Chem. Soc. 2016, 138(3), 920-925, DOI: 10.1021/jacs.5b11034 ; Polymer-Metal-Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations
其他名称：H2(BA-BDC);1,4-Benzenedicarboxylic acid, 2,5-bis(2-propenyloxy)- ; 2,5-Bis(2-propen-1-yloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)-1,4-benzenedicarboxylic acid; 2,5-Bis(allyloxy)terephthalic acid
CAS：149590-60-3
结构信息
| 分子式 | C14H14O6 | 分子量 | 278.25736 | ||
| 性状照片 | |||||
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料：MTV-MOF-5-H [r2]; [Zn2(2,5-BA-bdc)2(dabco)]n [r3]; [Cu2(BA-bdc)2(bpy)]n [r4]; UiO-66-BAT [r5]
表征图谱
参考文献
1) Steuer, Martin; Rehahn, Matthias; Ballauff, Matthias; Makromolekulare Chemie 1993, 194(8), 2395-410, Synthesis and characterization of rigid-rod polyesters bearing 3-hydroxypropyl and 3-acetoxypropyl side groups
2) Deng, Hexiang; Doonan, Christian J.; Furukawa, Hiroyasu; Ferreira, Ricardo B.; Towne, John; Knobler, Carolyn B.; Wang, Bo; Yaghi, Omar M.; Science 2010, 327(5967), 846-850, DOI: 10.1126/science.1181761 ; Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks5) Helal, Aasif; Usman, Muhammad; Arafat, Md. Eyasin; Abdelnaby, Mahmoud M.; J. Ind. Eng. Chem. 2020, 89, 104-110, DOI: 10.1016/j.jiec.2020.05.016 ; Allyl functionalized UiO-66 metal-organic framework as catalyst for synthesis of cyclic carbonates by carbon dioxide cycloaddition
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