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2,5-Bis(allyloxy)terephthalic acid
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2,5-Bis(allyloxy)terephthalic acid
CAS:149590-60-3 分子式:C14H14O6 分子量:278.25736
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产品名称:2,​5-​Di(allyloxy)​terephthalic acid
其他名称:H2(BA-BDC);1,​4-​Benzenedicarboxylic acid, 2,​5-​bis(2-​propenyloxy)​- ​; 2,​5-​Bis(2-​propen-​1-​yloxy)​-​1,​4-​benzenedicarboxylic acid; 2,​5-​Bis(allyloxy)​-​1,​4-​benzenedicarboxylic acid; 2,​5-​Bis(allyloxy)​terephthalic acid
CAS:149590-60-3
结构信息
分子式 C14H14O6 分子量 278.25736
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:MTV-MOF-5-H [r2]; [Zn2(2,5-BA-bdc)2(dabco)]n [r3]; [Cu2(BA-bdc)2(bpy)]n [r4]; UiO-​66-​BAT [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Steuer, Martin; Rehahn, Matthias; Ballauff, Matthias; Makromolekulare Chemie 1993, 194(8), 2395-410, Synthesis and characterization of rigid-​rod polyesters bearing 3-​hydroxypropyl and 3-​acetoxypropyl side groups
2) Deng, Hexiang; Doonan, Christian J.; Furukawa, Hiroyasu; Ferreira, Ricardo B.; Towne, John; Knobler, Carolyn B.; Wang, Bo; Yaghi, Omar M.; Science 2010, 327(5967), 846-850, DOI: 10.1126/science.1181761 ; Multiple Functional Groups of Varying Ratios in Metal-​Organic Frameworks
3) Henke, Sebastian; Schneemann, Andreas; Wuetscher, Annika; Fischer, Roland A.; J. Am. Chem. Soc. 2012, 134(22), 9464-9474, DOI: 10.1021/ja302991b ; Directing the Breathing Behavior of Pillared-​Layered Metal-​Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents
4) Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A.; Ploskonka, Ann M.; DeCoste, Jared B.; Cohen, Seth M.; J. Am. Chem. Soc. 2016, 138(3), 920-925, DOI: 10.1021/jacs.5b11034 ; Polymer-​Metal-​Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations

5) Helal, Aasif; Usman, Muhammad; Arafat, Md. Eyasin; Abdelnaby, Mahmoud M.; J. Ind. Eng. Chem. 2020, 89, 104-110, DOI: 10.1016/j.jiec.2020.05.016 ; Allyl functionalized UiO-​66 metal-​organic framework as catalyst for synthesis of cyclic carbonates by carbon dioxide cycloaddition

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2,5-Bis(allyloxy)terephthalic acid
2,5-Bis(allyloxy)terephthalic acid