产品名称:1,3-Bis(1,2,4-triazol-1-yl)propane其他名称:btp ; btrp ; H2btp;1,1'-(1,3-Propanediyl)bis[1H-1,2,4-triazole]; 1,3-Di(1H-1,2,4-triazol-1-yl)propane CAS:148854-47-1
结构信息
分子式 |
C7H10N6 |
分子量 |
178.1945 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cu(btp)2(MeCN)(H2O)] [r1]; [Cu6(btp)3(P2W18O62)]·3H2O [r3]; [Fe(btp)3] [r4];
表征图谱
参考文献
1) Van Albada, Gerard A.; Guijt, Reinier C.; Haasnoot, Jaap G.; Lutz, Martin; Spek, Anthony L.; Reedijk, Jan; Eur. J. Inorg. Chem. 2000, (1), 121-126, DOI: 10.1002/(SICI)1099-0682(200001)2000:13.0.CO;2-D ;
2) Wang, Xin-Long; Qin, Chao; Wang, En-Bo; Su, Zhong-Min; Li, Yang-Guang; Xu, Lin; Angew. Chem., Int. Ed. 2006, 45(44), 7411-7414, DOI: 10.1002/anie.200603250 ; Self-assembly of nanometer-scale [Cu24I10L12]14+ cages and ball-shaped Keggin clusters into a (4,12)-connected 3D framework with photoluminescent and electrochemical properties
3) Tian, Ai-xiang; Ying, Jun; Peng, Jun; Sha, Jing-quan; Han, Zhan-gang; Ma, Jian-fang; Su, Zhong-min; Hu, Ning-hai; Jia, Heng-qing; Inorg. Chem. 2008, 47(8), 3274-3283, DOI: 10.1021/ic7023082 ; Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility
4) Gu, Zhi-Guo; Xu, Yi-Fan; Zhou, Xin-Hui; Zuo, Jing-Lin; You, Xiao-Zeng; Cryst. Growth & Des. 2008, 8(4), 1306-1312, DOI: 10.1021/cg7010666 ; Assembly of Iron(II)-Triazole Polymers from 1D Chains to 3D Interpenetrated Frameworks: Syntheses, Structures, and Magnetic Properties
5) Semitut, Evgeny Yu.; Sukhikh, Taisiya S.; Filatov, Evgeny Yu.; Anosova, Galina A.; Ryadun, Alexey A.; Kovalenko, Konstantin A.; Potapov, Andrei S.; Cryst. Growth & Des. 2017, 17(10), 5559-5567, DOI: 10.1021/acs.cgd.7b01133 ; Synthesis, Crystal Structure, and Luminescent Properties of Novel Zinc Metal-Organic Frameworks Based on 1,3-Bis(1,2,4-triazol-1-yl)propane