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5,5'-(1,3-phenylenebis(methylene))bis(oxy)diisophthalic acid
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5,5'-(1,3-phenylenebis(methylene))bis(oxy)diisophthalic acid
CAS:147566-76-5 分子式:C24H18O10 分子量:466.39372
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产品名称:5,​5'-​[1,​3-​Phenylenebis(methyle​neoxy)​]​bis[1,​3-​benzenedicarboxylic acid]
其他名称:5,​5'-​(1,​3-​phenylenebis(methylene)​)​bis(oxy)​diisophthalic acid
CAS:147566-76-5
结构信息
分子式 C24H18O10 分子量 466.39372
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Zafar, Abdullah; Yang, Ji; Geib, Steven J.; Hamilton, Andrew D.; Tetrahedron Lett. 1996, 37(14), 2327-2330, DOI: 10.1016/0040-4039(96)00287-0 ; Linked bis-​isophthalic acid derivatives as building blocks in the design of self-​assembling structures
2) Perry, John J., IV; Kravtsov, Victor Ch.; McManus, Gregory J.; Zaworotko, Michael J.; Journal of the American Chemical Society 2007, 129(33), 10076-10077, DOI: 10.1021/ja0734952 ; Bottom up Synthesis That Does Not Start at the Bottom: Quadruple Covalent Cross-​Linking of Nanoscale Faceted Polyhedra
3) Pan, Zhaorui; Zheng, Hegen; Wang, Tianwei; Song, You; Li, Yizhi; Guo, Zijian; Batten, Stuart R.; Inorg. Chem. 2008, 47(20), 9528-9536, DOI: 10.1021/ic801221r ; Hydrothermal Synthesis, Structures, and Physical Properties of Four New Flexible Multicarboxylate Ligands-​Based Compounds
4) Ma, Tian; Li, Ming-Xing; Wang, Zhao-Xi; Zhang, Jin-Cang; Shao, Min; He, Xiang; Cryst. Growth & Des. 2014, 14(8), 4155-4165, DOI: 10.1021/cg500751e ; Structural Diversity, Luminescence, and Magnetic Properties of Eight Co(II)​/Zn(II) Coordination Polymers Constructed from Semirigid Ether-​Linked Tetracarboxylates and Bend Dipyridyl-​Triazole Ligands

5) Pei, Wen-Yuan; Xu, Guohai; Yang, Jin; Wu, Hui; Chen, Banglin; Zhou, Wei; Ma, Jian-Fang; Journal of the American Chemical Society 2017, 139(22), 7648-7656, DOI: 10.1021/jacs.7b03169 ; Versatile Assembly of Metal-​Coordinated Calix[4]​resorcinarene Cavitands and Cages through Ancillary Linker Tuning6) Wei, Ming-Hsin; Li, Boyu; David, R. L. Ameri; Jones, Simon C.; Sarohia, Virendra; Schmitigal, Joel A.; Kornfield, Julia A.; Science 2015, 350(6256), 72-75, DOI: 10.1126/science.aab0642 ; Megasupramolecules for safer, cleaner fuel by end association of long telechelic polymers

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5,5'-(1,3-phenylenebis(methylene))bis(oxy)diisophthalic acid
5,5'-(1,3-phenylenebis(methylene))bis(oxy)diisophthalic acid