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3,3''''-Dihydroxy-2',2'',2''',5',5'',5'''-hexamethyl[1,1':4',1'':4'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarboxylic acid
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3,3''''-Dihydroxy-2',2'',2''',5',5'',5'''-hexamethyl[1,1':4',1'':4'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarboxylic acid
3,3''''-Dihydroxy-2',2'',2''',5',5'',5'''-hexamethyl[1,1':4',1'':4'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarboxylic acid
CAS:1382735-30-9 分子式:C38H34O6 分子量:586.67296
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产品名称:3,​3''''-​Dihydroxy-​2',​2'',​2''',​5',​5'',​5'''-​hexamethyl[1,​1':4',​1'':4'',​1''':4''',​1''''-​quinquephenyl]​-​4,​4''''-​dicarboxylicacid
其他名称:DOT V ; 5-mer-HCA ;
CAS:1382735-30-9
结构信息
分子式 C38H34O6 分子量 586.67296
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:MOF-74 V/IRMOF-74 V [r1]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Deng, Hexiang; Grunder, Sergio; Cordova, Kyle E.; Valente, Cory; Furukawa, Hiroyasu; Hmadeh, Mohamad; Gandara, Felipe; Whalley, Adam C.; Liu, Zheng; Asahina, Shunsuke; Kazumori, Hiroyoshi; O'Keeffe, Michael; Terasaki, Osamu; Stoddart, J. Fraser; Yaghi, Omar M.; Science 2012, 336(6084), 1018-1023, DOI: 10.1126/science.1220131 ; Large-​Pore Apertures in a Series of Metal-​Organic Frameworks
2) Grunder, Sergio; Valente, Cory; Whalley, Adam C.; Sampath, Srinivasan; Portmann, Juerg; Botros, Youssry Y.; Stoddart, J. Fraser; Chem.-Eur. J. 2012, 18(49), 15632-15649, DOI: 10.1002/chem.201201985 ; Molecular Gauge Blocks for Building on the Nanoscale
3) Foster, Michael E.; Azoulay, Jason D.; Wong, Bryan M.; Allendorf, Mark D.; Chem. Sci. 2014, 5(5), 2081-2090, DOI: 10.1039/C4SC00333K ; Novel metal-​organic framework linkers for light harvesting applications

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3,3''''-Dihydroxy-2',2'',2''',5',5'',5'''-hexamethyl[1,1':4',1'':4'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarboxylic acid
3,3''''-Dihydroxy-2',2'',2''',5',5'',5'''-hexamethyl[1,1':4',1'':4'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarboxylic acid