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3,3''-dihydroxy-4''-(methoxycarbonyl)-2',5'-dimethyl-[1,1':4',1''-terphenyl]-4-carboxylic acid
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3,3''-dihydroxy-4''-(methoxycarbonyl)-2',5'-dimethyl-[1,1':4',1''-terphenyl]-4-carboxylic acid
3,3''-dihydroxy-4''-(methoxycarbonyl)-2',5'-dimethyl-[1,1':4',1''-terphenyl]-4-carboxylic acid
CAS:1382735-24-1 分子式:C26H16N2O4 分子量:420.41624
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产品名称:3,3''-dihydroxy-4''-(methoxycarbonyl)-2',5'-dimethyl-[1,1':4',1''-terphenyl]-4-carboxylic acid
其他名称:H4-TPP
CAS:1382735-24-1
结构信息
分子式 C22H18O6 分子量 378.37472
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:IRMOF-74-III [r1]; Ni-TPP [r3]
表征图谱
HNMR
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Foster, M.; Azoulay, J.; Wong, B.; Allendorf, M.; Chem. Sci. 2014, 5(5), 2081-2090, DOI:10.1039/C4SC00333K ; Novel metal–organic framework linkers for light harvesting applications 
2) Mutruc, D.; Goulet-Hanssens, A.; Fairman, S.; Wahl, S.; Zimathies, A.; Knie, C.; Hecht, S.; Angew. Chem., Int. Ed. 2019, 58(37), 12862-12867, 10.1021/acsami.9b22445 ; Metal–Organic Framework-Based Microfluidic Impedance Sensor Platform for Ultrasensitive Detection of Perfluorooctanesulfonate 
3) 2) Zheng, J.; Barpaga, D.; Trump, B.; Shetty, M.; Fan, Y.; Bhattacharya, P.; Jenks, J.; Su, C.-Y.; Brown, C.; Maurin, G.; McGrail, B. P.; Motkuri, R. K. J. Am. Chem. Soc. 2020, 142, 3002– 3012, DOI: 10.1021/jacs.9b11963
4) Zheng, J.; Vemuri, R. S.; Estevez, L.; Koech, P. K.; Varga, T.; Camaioni, D. M.; Blake, T. A.; McGrail, B. P.; Motkuri, R. K.  J. Am. Chem. Soc. 2017, 139 (31), 10601– 10604, DOI: 10.1021/jacs.7b04872 ; Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications 
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3,3''-dihydroxy-4''-(methoxycarbonyl)-2',5'-dimethyl-[1,1':4',1''-terphenyl]-4-carboxylic acid
3,3''-dihydroxy-4''-(methoxycarbonyl)-2',5'-dimethyl-[1,1':4',1''-terphenyl]-4-carboxylic acid