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4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile
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4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile
4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile
CAS:136809-42-2 分子式:C32H16N2 分子量:428.48284
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产品名称:4,​4'-​(9,​10-​Anthracenediyldi-​2,​1-​ethynediyl)​bis[benzonitrile]
其他名称:
CAS:136809-42-2
结构信息
分子式 C32H16N2 分子量 428.48284
性状照片  
性质说明
1) 可溶于DCM、DMF、DMSO等
2) 2-8℃密封保存
合成应用
1) 可作为单体用于合成COF材料:
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Akiyama, S.; Nakatsuji, S.; Nomura, K.; Matsuda, K.; Nakashima, K.; J. Chem. Soc., Chem. Commun. 1991, (14), 948-950, DOI:10.1039/C39910000948 ; Direct C≡C triple bond formation from the C=C double bond with potassium tert-​butoxide in dimethylformamide containing trace amounts of oxygen
2) Nguyen, P.; Todd, S.; Van den Biggelaar, D.; Taylor, N.; Marder, T.; Wittmann, F.; Friend, R.; Synlett 1994, (4), 299-301, DOI: 10.1055/s-1994-22837 ; Facile route to highly fluorescent 9,​10-​bis(p-​R-​phenylethynyl)​anthracene chromophores via palladium-​copper catalyzed cross-​coupling
3) Fudickar, W.; Linker, T.; Chem.- Eur. J. 2011), 17(49), 13661-13664, DOI: 10.1002/chem.201102230 ; Reversible Photooxygenation of Alkynylanthracenes: Chemical Generation of Singlet Oxygen under Very Mild Conditions
4) Fudickar, W.; Linker, T.; J. Am. Chem. Soc. 2012, 134(36), 15071-15082, DOI: 10.1021/ja306056x ; Why Triple Bonds Protect Acenes from Oxidation and Decomposition

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4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile
4,4'-(9,10-anthracenediyldi-2,1-ethynediyl)bis-Benzonitrile