NH2-MIL-88B(Fe)
NH2-MIL-88B(Fe)
CAS:1341134-09-5
分子式:C24H15Fe3N3O13
分子量:720.92
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品牌 / 纯度 / 包装
材料名称：NH2-MIL-88B(Fe)
其他名称：NA
CAS：1341134-09-5
其他名称：NA
CAS：1341134-09-5
结构信息
| 单位分子式 | C24H15N3O13Fe3 | 单位分子量 | 720.92 | ||
| 配位金属 | Fe | 配体 | 2-氨基对苯二甲酸（CAS：10312-55-7） | ||
| 孔径 | NA | 孔容 | NA | ||
| 比表面 | N2测BET基本无吸附 | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 棕褐色粉末 |  |
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| 粒径 | 100*300nm 纺锤形晶粒 | |||
稳定性
1) NH2-MIL-88B(Fe) 在空气中稳定，在水溶液和酸性条件下较稳定。
2) 高热稳定性、热分解温度大于400℃
2) 高热稳定性、热分解温度大于400℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化3小时
2) 建议使用前150度（真空）烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 储气材料和吸附材料;具有特殊的“呼吸”效应
2) 作为路易斯酸催化剂
2) 作为路易斯酸催化剂
表征图谱
参考文献
1) C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Férey, Science 2007, 315, 1828-1831, DOI: 10.1126/science.1137975 ; Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks
2) P. Sivakumar, S. Priyatharshni, K. B. Nagashanmugam, A. Thanigaivelan, K. Kumar, Mater. Res. Express 2017, 4, 085023, DOI: 10.1088/2053-1591/aa822f ; Chitosan capped nanoscale Fe-MIL-88B-NH2 metal-organic framework as drug carrier material for the pH responsive delivery of doxorubicin;
3) Shenlong Zhao, Huajie Yin, Lei Du, Liangcan He, Kun Zhao, Lin Chang, Geping Yin, Huijun Zhao, Shaoqin Liu, Zhiyong Tang. ACS Nano, 2014, 8(12): 12660-12668. DOI: 10.1021/nn505582e. Carbonized Nanoscale Metal-Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction. 【文献解读】;
4) Xiyi Li, Yunhong Pi, Liqiong Wu, Qibin Xia, Junliang Wu, Zhong Li, Jing Xiao. Applied Catalysis B: Environmental, 2017, 202: 653-663. DOI: 10.1016/j.apcatb.2016.09.073. Facilitation of the visible light-induced Fenton-like excitation of H₂O₂ via heterojunction of g-C₃N₄/NH₂-Iron terephthalate metal-organic framework for MB degradation. 【文献解读】;
5) Weiqing Xu, Lei Jiao, Hongye Yan, Yu Wu, Lijuan Chen, Wenling Gu, Dan Du, Yuehe Lin, Chengzhou Zhu. ACS Applied Materials & Interfaces, 2019, 11(24): 22096-22101. DOI: 10.1021/acsami.9b03004. Glucose Oxidase-Integrated Metal−Organic Framework Hybrids as Biomimetic Cascade Nanozymes for Ultrasensitive Glucose Biosensing. 【文献解读】;
6) Donghua Xie, Yue Ma, Yue Gu, Hongjian Zhou, Haimin Zhang, Guozhong Wang, Yunxia Zhang, Huijun Zhao. Journal of Materials Chemistry A, 2017, 5(46): 23794-23804. DOI: 10.1039/c7ta07934f. Bifunctional NH₂-MIL-88(Fe) metal–organic framework nanooctahedra for highly sensitive detection and efficient removal of arsenate in aqueous media. 【文献解读】;
7) Minh-Hao Pham, Gia-Thanh Vuong, Anh-Tuan Vu, Trong-On Do. Langmuir, 2011, 27(24): 15261-15267. DOI: 10.1021/la203570h. Novel Route to Size-Controlled FeMIL-88B(NH₂) Metal-Organic Framework Nanocrystals. 【文献解读】
