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UIO-66-COOH
UIO-66-COOH
CAS:1334722-04-1 分子式:C54H22O44Zr6.H6 分子量:1928.12
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材料名称:UIO-66(Zr)-COOH
其他名称:NA
CAS:1334722-04-1
结构信息
单位分子式 C54H18O44Zr6-6.H+ 单位分子量 1918.90
配位金属 Zr 配体 偏苯三酸 (CAS:528-44-9)
孔径 0.8nm, 1.1nm 孔容  
比表面 BET比表面600-700m2/g 
模拟结构  
产品性状
产品形貌 类白色粉末 
Off-White
 
粒径 200-800nm
稳定性
1)  COOH-UIO-66 性质稳定,在水溶液和酸性条件下稳定。
2)高热稳定性、热分解温度大于350℃
保存和活化方法
1) 常温或低温条件下,干燥密封保存
2) 建议使用前150度(真空)烘箱活化3-5小时
其他特性
荧光:NA
应用领域
1) 储气材料和吸附材料
2) COOH-UIO-66支链羧基官能团适合进一步衍生,与氨基酸、多肽、蛋白质键和;或与稀土金属络合作为探针
表征图谱
XRD
XRD-UIO-66-COOH
SEM
SEM-UIO-66-COOH
BET
BET-UIO-66-COOH
FTIR
IR-UIO-66-COOH s
参考文献
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) Z. Hu, Y. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 2015, 54, 4862-4868, DOI: 10.1021/acs.inorgchem.5b00435 ; A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs
3) Y. Khabzina,  J. Dhainaut, M. Ahlhelm, H.-J. Richter,  H. Reinsch, N. Stock, D. Farrusseng, Ind. Eng. Chem. Res. 2018, 57, 24, 8200-8208, DOI: 10.1021/acs.iecr.8b00808 ; Synthesis and Shaping Scale-up Study of Functionalized UiO-66 MOF for Ammonia Air Purification Filters;
4)Qingyuan Yang, Andrew D. Wiersum, Philip L. Llewellyn, Vincent Guillerm, Christian Serred, Guillaume Maurin; ChemComm, 2011, 47, 96039605; DOI 10.1039/c1cc13543k; Functionalizing porous zirconium terephthalate UiO-66(Zr) for natural gas upgrading: a computational exploration【文献解读】;
5)Florence Ragon, Betiana Campo, Qingyuan Yang, Charlotte Martineau, Andrew D. Wiersum, Ana Lago, Vincent Guillerm, Callum Hemsley, Jarrod F. Eubank, Muthusamy Vishnuvarthan, Francis Taulelle, Patricia Horcajada, Alexandre Vimont, Philip L. Llewellyn, Marco Daturi, Sabine Devautour-Vinot, Guillaume Maurin, Christian Serre, Thomas Devic, Guillaume Clet; Journal of Materials Chemistry A, 2015, 3, 3294-3309; DOI:10.1039/c4ta03992k; Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties文献解读】;
6) Shyam Biswas, Jian Zhang, Zhibao Li, Ying-Ya Liu, Maciej Grzywa, Lixian Sun, Dirk Volkmer, Pascal Van Der Voort; Dalton Transactions, 2013, 42, 4730-4737; DOI:10.1039/c3dt32288b; Enhanced Selectivity of CO₂ over CH₄ in Sulphonate-, Carboxylate- and Iodo-Functionalized UiO-66 Frameworks【文献解读】;
7) Shixiong Li, Shengli Sun, Haizhen Wu, Chaohai Wei, Yun Hu; Catalysis Science & Technology, 2018, 8, 1696-1703; DOI10.1039/c7cy02622f; Effects of electron-donating groups on the photocatalytic reaction of MOFs 【文献解读】;
8) Xudong Zhao, Yaxin Wang, Yali Li, Wenjuan Xue, Jian Li, Huiyuan Wu, Yuezhong Zhang, Bingzheng Li, Wen Liu, Zhuqing Gao, Hongliang Huang; Journal of Chemical & Engineering Data, 2019, 64, 2728-2735; DOI :10.1021/acs.jced.9b00130; Synergy Effect of Pore Structure and Amount of Carboxyl Site for Effective Removal of Pb²⁺ in Metal−Organic Frameworks【文献解读

 

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