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1,3-Benzenedicarboxylic acid, 5,5',5'',5'''-[1,2,4,5-benzenetetrayltetrakis(methyleneoxy)]tetrakis-
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1,3-Benzenedicarboxylic acid, 5,5',5'',5'''-[1,2,4,5-benzenetetrayltetrakis(methyleneoxy)]tetrakis-
1,3-Benzenedicarboxylic acid, 5,5',5'',5'''-[1,2,4,5-benzenetetrayltetrakis(methyleneoxy)]tetrakis-
CAS:1330041-38-7 分子式:C42H30O20 分子量:854.6756
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产品名称:5,​5',​5'',​5'''-​[1,​2,​4,​5-​Benzenetetrayltetrak​is(methyleneoxy)​]​tetrakis[1,​3-​benzenedicarboxylicacid]
其他名称:;
CAS:1330041-38-7
结构信息
分子式 C42H30O20 分子量 854.6756
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:tbo-MOF-1 2[r1, r2, r3]; MJ3 [r5]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Eubank, Jarrod F.; Mouttaki, Hasnaa; Cairns, Amy J.; Belmabkhout, Youssef; Wojtas, Lukasz; Luebke, Ryan; Alkordi, Mohamed; Eddaoudi, Mohamed; J. Am. Chem. Soc. 2011, 133(36), 14204-14207, DOI: 10.1021/ja205658j ; The Quest for Modular Nanocages: tbo-​MOF as an Archetype for Mutual Substitution, Functionalization, and Expansion of Quadrangular Pillar Building Blocks
2) Belmabkhout, Youssef; Mouttaki, Hasnaa; Eubank, Jarrod F.; Guillerm, Vincent; Eddaoudi, Mohamed; RSC Adv. 2014, 4(109), 63855-63859, DOI: 10.1039/C4RA12432D ; Effect of pendant isophthalic acid moieties on the adsorption properties of light hydrocarbons in HKUST-​1-​like tbo-​MOFs: application to methane purification and storage
3) Spanopoulos, Ioannis; Tsangarakis, Constantinos; Klontzas, Emmanuel; Tylianakis, Emmanuel; Froudakis, George; Adil, Karim; Belmabkhout, Youssef; Eddaoudi, Mohamed; Trikalitis, Pantelis N.; J. Am. Chem. Soc. 2016, 138(5), 1568-1574, DOI: 10.1021/jacs.5b11079 ; Reticular Synthesis of HKUST-​like tbo-​MOFs with Enhanced CH4 Storage
4) Chernikova, Valeriya; Shekhah, Osama; Spanopoulos, Ioannis; Trikalitis, Pantelis N.; Eddaoudi, Mohamed; Chem. Commun. 2017, 53(46), 6191-6194, DOI: 10.1039/C7CC03270F ; Liquid phase epitaxial growth of heterostructured hierarchical MOF thin films

5) Jurcic, Monika; Peveler, William J.; Savory, Christopher N.; Bucar, Dejan-Kresimir; Kenyon, Anthony J.; Scanlon, David O.; Parkin, Ivan P.; ACS Appl. Mater.& Interfaces 2019, 11(12), 11618-11626, DOI: 10.1021/acsami.8b22385 ; Sensing and Discrimination of Explosives at Variable Concentrations with a Large-​Pore MOF as Part of a Luminescent Array

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1,3-Benzenedicarboxylic acid, 5,5',5'',5'''-[1,2,4,5-benzenetetrayltetrakis(methyleneoxy)]tetrakis-
1,3-Benzenedicarboxylic acid, 5,5',5'',5'''-[1,2,4,5-benzenetetrayltetrakis(methyleneoxy)]tetrakis-