NH2-MIL-125(Ti) | CAS: 1309760-94-8 | CHEMSOON

材料名称：NH2-MIL-125Ti
其他名称：NA
CAS：1309760-94-8

结构信息

单位分子式	C48H5N6O36Ti8	单位分子量	1624.5079
配位金属	Ti	配体	2-氨基对苯二酸（CAS：10312-55-7）
孔径	0.6nm*0.8nm	孔容
比表面	BET比表面 1100-1200 m2/g
模拟结构

产品性状

产品形貌	亮黄色粉末 Bright Yellow Powder
粒径	500nm-1um round particles

稳定性

1) NH2-MIL-125(Ti)在空气和水溶液中稳定
2）热分解温度约350℃

保存和活化方法

1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化3小时

其他特性

应用领域

1) 气体与有机污染物吸附分离
2) NH2-MIL-125(Ti) 具有很好的光催化活性，可以光催化降解CO2和有机物

表征图谱

XRD

SEM

BET

FTIR

参考文献

1) M. Dan-Hardi, C. Serre, T. Frot, L. Rozes, G. Maurin, C. Sanchez, G Férey, J. Am. Chem. Soc. 2009, 10857-10859, DOI: 10.1021/ja903726m ; A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate；

2) Hou Wang, Xingzhong Yuan, Yan Wu, Guangming Zeng, Xiaohong Chen, Lijian Leng, Zhibin Wu, Longbo Jiang, Hui Li;Journal of Hazardous Materials, 2015, 286, 187-194; DOI：10.1016/j.jhazmat.2014.11.039; Facile synthesis of amino-functionalized titanium metal−organic frameworks and their superior visible-light photocatalytic activity for Cr(VI) reduction【文献解读】；

3）Fei Li, Dengke Wang, Qiu-Ju Xing, Gang Zhou, Shan-Shan Liu, Yan Li, Ling-Ling Zheng, Peng Ye, Jian-Ping Zou; Applied Catalysis B: Environmental, 2019, 243, 621-628; DOI：10.1016/j.apcatb.2018.10.043; Design and syntheses of MOF/COF hybrid materials via postsynthetic covalent modification: An efficient strategy to boost the visible-light-driven photocatalytic performance【文献解读】；

4）Yanghe Fu, Dengrong Sun, Yongjuan Chen, Renkun Huang, Zhengxin Ding, Xianzhi Fu, Zhaohui Li; Angewandte Chemie International Edition, 2012, 51, 3364-3367; DOI：10.1002/anie.201108357;An Amine-Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO₂ Reduction【文献解读】；

5）Yusuke Isaka, Yudai Kawase, Yasutaka Kuwahara, Kohsuke Mori, Hiromi Yamashita*; Angewandte Chemie, 2019, 131, 5456-5460; DOI：10.1002/anie.201901961；Two-Phase System Utilizing Hydrophobic Metal–Organic Frameworks (MOFs) for Photocatalytic Synthesis of Hydrogen Peroxide【文献解读】；

6）Philipp Brandt, Alexander Nuhnen, Marcus Lange, Jens Mollmer, Oliver Weingart, Christoph Janiak*;ACS Applied Materials & Interfaces, 2019, 11, 17350-17358; DOI：10.1021/acsami.9b00029; Metal−Organic Frameworks with Potential Application for SO₂ Separation and Flue Gas Desulfurization【文献解读】；

7）Xiaolang Chen, Shuning Xiao, Hao Wang, Wenchao Wang, Yong Cai, Guisheng Li, Minghua Qiao, Jian Zhu, Hexing Li, Dieqing Zhang*, Yunfeng Lu*; Angewandte Chemie International Edition, 2020, 59, 17182-17186；DOI：10.1002/anie.202002375； MOFs Conferred with Transient Metal Centers for Enhanced Photocatalytic Activity【文献解读】；

8）Frederik Vermoortele, Michael Maes, Peyman Z. Moghadam, Matthew J. Lennox, Florence Ragon, Mohammed Boulhout, Shyam Biswas, Katrien G. M. Laurier, Isabelle Beurroies, Renaud Denoyel, Maarten Roeffaers, Norbert Stock, Tina Düren, Christian Serre, Dirk E. De Vos*;Journal of the American Chemical Society, 2011, 133, 18526-18529; DOI：10.1021/ja207287h; p-Xylene-Selective Metal–Organic Frameworks: A Case of Topology-Directed Selectivity【文献解读】；

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