产品名称:4,4'-Bis(2-methyl-imidazol-1-ylmethyl)biphenyl其他名称:bmimbp ; bis-Im-diPh;1,1'-[[1,1'-Biphenyl]-4,4'-diylbis(methylene)]bis[2-methyl-1H-imidazole] CAS:1283072-03-6
结构信息
分子式 |
C22H22N4 |
分子量 |
342.43688 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:[Cd(bmimbp)(bdc)] [r3]
表征图谱
参考文献
1) Liu, Tong-Fei; Wu, Wan-Fei; Wan, Chong-Qing; He, Cui-Hong; Jiao, Cui-Huan; Cui, Guang-Hua; J. Coord. Chem. 2011, 64(6), 975-986, DOI: 10.1080/00958972.2011.559543 ; From discrete dinuclear to 1-D and 2-D structures. Nickel dipicolinate complexes with flexible bis(imidazole) ligands
2) Jacobs, Tia; Lloyd, Gareth O.; Gertenbach, Jan-Andre; Mueller-Nedebock, Kristian K.; Esterhuysen, Catharine; Barbour, Leonard J.; Angew. Chem., Int. Ed. (2012), 51(20), 4913-4916, DOI: 10.1002/anie.201201281 ; In situ X-ray Structural Studies of a Flexible Host Responding to Incremental Gas Loading
3) Sun, Di; Yan, Zhi-Hao; Deng, Yong-Kai; Yuan, Shuai; Wang, Lei; Sun, Dao-Feng; CrystEngComm 2012, 14(23), 7856-7860, DOI: 10.1039/c2ce25706h ; Two novel entangled metal-organic networks constructed from 4,4'-bis(2-methylimidazol-1-ylmethyl)biphenyl and dicarboxylates: From polycatenated 2D + 2D 3D framework to polyrotaxane-like 2D + 2D 2D layer
4) Fan, Yan; Hu, Dong-Cheng; Yao, Xiao-Qiang; Yang, Yun-Xia; Liu, Jia-Cheng; New J. Chem. 2016, 40(6), 5010-5018, DOI: 10.1039/C6NJ00065G ; Four cobalt(II) complexes based on a new tricarboxylate with a naphthalene ring and different N-containing ligands: synthesis, crystal structures and magnetic properties
5) Dai, Jian; He, Gaohong; Ruan, Xuehua; Zheng, Wenji; Pan, Yu; Yan, Xiaoming; Int. J. Hydrogen Energy 2016, 41(25), 10923-10934, DOI: 10.1016/j.ijhydene.2016.04.059 ; Constructing a rigid crosslinked structure for enhanced conductivity of imidazolium functionalized polysulfone hydroxide exchange membrane