产品名称:2,5-Bis(2-methoxyethoxy)terephthalic acid其他名称:H2BME-bdc; H2BDC-2OEtOMe;2,5-Bis(2-methoxyethoxy)-1,4-benzenedicarboxylic acid CAS:1265529-85-8
结构信息
分子式 |
C14H18O8 |
分子量 |
314.28792 |
性状照片 |
|
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:M2(BME-bdc)2(dabco) (M2+ = Zn2+, Co2+, Ni2+, Cu2+) [r1]; UIO-66-2OEtOMe [r4]
表征图谱
参考文献
1) Henke, Sebastian; Schmid, Rochus; Grunwaldt, Jan-Dierk; Fischer, Roland A.; Chem.-Eur. J. 2010, 16(48), 14296-14306, DOI: 10.1002/chem.201002341 ; Flexibility and Sorption Selectivity in Rigid Metal-Organic Frameworks: The Impact of Ether-Functionalised Linkers
2) Henke, Sebastian; Fischer, Roland A.; J. Am. Chem. Soc. 2011, 133(7), 2064-2067, DOI: 10.1021/ja109317e ; Gated Channels in a Honeycomb-like Zinc-Dicarboxylate-Bipyridine Framework with Flexible Alkyl Ether Side Chains
3) Schneemann, Andreas; Vervoorts, Pia; Hante, Inke; Tu, Min; Wannapaiboon, Suttipong; Sternemann, Christian; Paulus, Michael; Wieland, D. C. Florian; Henke, Sebastian; Fischer, Roland A.; Chem. Mater 2018, 30(5), 1667-1676, DOI: 10.1021/acs.chemmater.7b05052 ; Different Breathing Mechanisms in Flexible Pillared-Layered Metal-Organic Frameworks: Impact of the Metal Center
4) Fast, Caleb D.; Woods, Jason; Lentchner, Jared; Makal, Trevor A.; Dalton Trans. 2019, 48(39), 14696-14704,DOI: 10.1039/c9dt03004b ; Stabilizing defects in metal-organic frameworks: pendant Lewis basic sites as capping agents in UiO-66-type MOFs toward highly stable and defective porous materials