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6-​(3.​5-​二羧基苯基)​烟酸
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6-​(3.​5-​二羧基苯基)​烟酸
5-(5-carboxypyridin-2-yl)benzene-1,3-dicarboxylic acid
CAS:1261935-37-8 分子式:C14H9NO6 分子量:287.22
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产品名称:6-​(3,​5-​dicarboxylphenyl)​nicotinic acid
其他名称:H3DCPN ; H3DNA;5-​(5-​Carboxy-​2-​pyridinyl)​-​1,​3-​benzenedicarboxylic acid
CAS:1261935-37-8
结构信息
分子式 C14H9NO6 分子量 287.22436
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:UMCM-​150N1 [r1]; [Co(HDCPN)​(4,​4'-​bibp)​]​ [r2]; [Ni(HDNA)​(bibp)​(H2O)​]​ [r4]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Park, Tae-Hong; Cychosz, Katie A.; Wong-Foy, Antek G.; Dailly, Anne; Matzger, Adam J.; Chem. Commun. 2011, 47(5), 1452-1454, DOI: 10.1039/C0CC03482G ; Gas and liquid phase adsorption in isostructural Cu3[biaryltricarboxylate]​2 microporous coordination polymers
2) Wang, Xiao-Xiao; Wang, Xiao-Qing; Niu, Xiao-Yan; Hu, Tuo-Ping; CrystEngComm 2016, 18(39), 7471-7477, DOI: 10.1039/C6CE01457G ; Three novel metal-​organic frameworks based on an unsymmetrical rigid carboxylate ligand for luminescence sensing of nitrobenzene derivatives and magnetic properties
3) Hu, Tuoping; Wang, Xiaoxiao; Xue, Zhijia; Zhang, Xiao; Wang, Xiaoqing; Polyhedron 2017, 127, 449-457, DOI: 10.1016/j.poly.2016.11.003 ; Structural control and magnetic properties of three Co(II) coordination polymers based on 6-​(3,​5-​dicarboxylphenyl)​nicotinic acid
4) Zhang, Yujuan; Gao, Lingling; Zhang, Jie; Wu, Haonan; Fan, Liming; Hu, Tuoping; J. Solid State Chem. 2019, 271, 40-46, DOI: 10.1016/j.jssc.2018.12.047 ; Structural diversity, magnetic properties, and luminescent sensing of four coordination polymers based on 6-​(3,​5-​dicarboxylphenyl)​nicotinic acid

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6-​(3.​5-​二羧基苯基)​烟酸
6-​(3.​5-​二羧基苯基)​烟酸