材料名称:MIL-100(Fe) 其他名称:BASOLITE F300 CAS:947723-08-2 / 1195763-37-1
结构信息
单位分子式 |
C18O15FFe3 |
单位分子量 |
642.717 |
配位金属 |
Fe |
配体 |
均苯三酸(CAS:554-95-0) |
孔径 |
窗口: 0.55-0.88nm; 孔径:2.5-2.9nm |
孔容 |
0.9 g/cm3 (微孔孔容 0.55g/cm3) |
比表面 |
BET比表面 1900 m2/g, |
模拟结构 |
 |
产品性状
产品形貌 |
浅橙色粉末 Orange Powder |
 |
粒径 |
1-10um不规则颗粒或团聚体 |
稳定性
1) MIL-100(Fe)在空气中稳定,在水溶液及酸性条件下中稳定
2)高热稳定性、热分解温度大于280℃
保存和活化方法
1) 常温或低温条件下,干燥密封保存
2) 建议使用前150度(真空)烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 气体(如二氧化碳)和污染物吸附
2) 作为路易斯酸催化剂具有良好的催化性能
表征图谱
参考文献
1) P. Horcajada, S. Surble, C. Serre, D.-Y. Hong, Y.-K. Seo, J.-S. Chang, J.-M. Greneche, I. Margiolaki, G. Férey, Chem. Commun., 2007, 2820-2822, DOI: 10.1039/B704325B Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores
2)
You-Kyong Seo, Ji Woong Yoon, Ji Sun Lee, U-Hwang Lee, Young Kyu Hwang, Chul-Ho Jun, Patricia Horcajada, Christian Serre, Jong-San Chang. Microporous and Mesoporous Materials, 2012, 157. DOI:10.1016/j.micromeso.2012.02.027. Large scale fluorine-free synthesis of hierarchically porous iron(Ⅲ
) trimesate MIL-100(Fe) with a zeolite MTN topology.【文献解读】;
3)Pia Küsgens , Marcus Rose , Irena Senkovska , Heidrun Fröde , Antje Henschel , Sven Siegle , Stefan Kaskel ;Volume 120, Issue 3, 15 April 2009, Pages 325-330;doi:10.1016/j.micromeso.2008.11.020;Characterization of metal-organic frameworks by water adsorption【
文献解读】;
4)
Camille Petit and Teresa J. Bandosz *;
Adv. Funct. Mater. 2011, 21, 2108–
2117;
DOI: 10.1002/adfm.201002517. Synthesis, Characterization, and Ammonia Adsorption Properties of Mesoporous Metal–
Organic Framework (MIL(Fe))–
Graphite Oxide Composites: Exploring the Limits of Materials Fabrication【文献解读】;
5) Guesh, Kiros; Caiuby, Clarice A. D.; Mayoral, Alvaro ; Diaz-Garcia, Manuel; Diaz, Isabel; Sanchez-Sanchez, Manuel;Crystal Growth & Design 2017 , 17(4), 1806-1813;DOI:10.1021/acs.cgd.6b01776;Sustainable Preparation of MIL-100(Fe) and Its Photocatalytic Behavior in the Degradation of Methyl Orange in Water【文献解读】