CAS 1195403-94-1|PSF|spiro-4-py|TPSBF|CHEMSOON-MOF/COF材料专业供应商

产品名称：4,4',4'',4'''-(9,9'-Spirobi[9H-fluorene]-2,2',7,7'-tetrayl)tetrakis[pyridine]
其他名称：PSF ; spiro-4-py ; TPSBF;2,2',7,7'-tetra(4-pyridyl)-9,9'-spirobifluorene
CAS：1195403-94-1

结构信息

分子式	C45H28N4		分子量	624.73062
性状照片

性质说明

1) 可溶于DMF、DMSO等
2) 室温密封保存

合成应用

1) 可作为配体用于合成MOF材料：[Cd(pda)0.5(spiro-4-py)0.5(HCOO)]·2H2O·DMF [r1]; Halogen-Bonded Organic Frameworks (XBOF) [r4]

表征图谱

HNMR

FTIR

HPLC

参考文献

1) Li, Xing; Zhang, Jie; Zhao, Yayun; Zhao, Xiuhua; Li, Feng; Li, Taohai; Li, H. L.; Chen, Liang; J. Mater. Chem. C 2015, 3(12), 6265-6270, DOI: 10.1039/C5TA00222B ; Trace amount CuII (ppm) and mixture design of CuII/PdII catalyzed Suzuki cross-coupling reactions based on the cooperative interaction of metal with a conjugated (pyridyl)spirobifluorene

2) Zhang, Jie; Li, Taohai; Zhao, Xiuhua; Zhao, Yayun; Li, Feng; Li, Xing; J. Colloid Interface Sci. 2016, 463, 13-21, DOI: 10.1016/j.jcis.2015.10.035 ; High catalytic active palladium nanoparticles gradually discharged from multilayer films to promote Suzuki, Heck and Sonogashira cross coupling reactions

3) An, Litao; Wang, Hao; Xu, Feng; Wang, Xin-Long; Wang, Fangming; Li, Jing; Inorg. Chem. 2016, 55(24), 12923-12929, DOI: 10.1021/acs.inorgchem.6b02332 ; Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers

4) Pop, Lidia; Grosu, Ioana Georgeta; Miclaus, Maria; Hadade, Niculina Daniela; Pop, Alexandra; Bende, Attila; Terec, Anamaria; Barboiu, Mihail; Grosu, Ion; Cryst. Growth Des. 2020, DOI: 10.1021/acs.cgd.0c01383 ; Halogen-Bonded Organic Frameworks of Perfluoroiodo- and Perfluorodiiodobenzene with 2,2′,7,7′-Tetrapyridyl-9,9′-spirobifluorene

1195403-94-1-CS017842.pdf

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