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4',4''''-(5'-(4-([2,2':6',2''-三吡啶]-4'-基)苯基)-[1,1':3',1''-三苯基]-4,4'-二基)二-2,2':6',2'''-三吡啶
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4',4''''-(5'-(4-([2,2':6',2''-三吡啶]-4'-基)苯基)-[1,1':3',1''-三苯基]-4,4'-二基)二-2,2':6',2'''-三吡啶
4',4''''-(5'-(4-([2,2':6',2''-terpyridin]-4'-yl)phenyl)-[1,1':3',1''-terphenyl]-4,4''-diyl)di-2,2':6',2''-terpyridine
CAS:1185464-11-2 分子式:C69H45N9 分子量:1000.1559
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产品名称:1,​3,​5-​tris[4-​(4'-​2,​2':6',​2''-​terpyridyl)​phenyl]​benzene
其他名称:TPY;4',​4''''-​[5'-​(4-​[2,​2':6',​2''-​Terpyridin]​-​4'-​ylphenyl)​[1,​1':3',​1''-​terphenyl]​-​4,​4''-​diyl]​bis[2,​2':6',​2''-​terpyridine]
CAS:1185464-11-2
结构信息
分子式 C69H45N9 分子量 1000.1559
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料: (CONASHs) 1-​Zn [r5]
2)可用于光致发光配位纳米片
表征图谱
HNMR
MS
FTIR
NA
HPLC
NA
参考文献
1) Cavazzini, Marco; Quici, Silvio; Scalera, Chiara; Puntoriero, Fausto; La Ganga, Giuseppina; Campagna, Sebastiano; Inorg. Chem. 2009, 48(17), 8578-8592, DOI: 10.1021/ic9006108 ; Synthesis, Characterization, Absorption Spectra, and Luminescence Properties of Multinuclear Species Made of Ru(II) and Ir(III) Chromophores
2) Zheng, Zhikun; Opilik, Lothar; Schiffmann, Florian; Liu, Wei; Bergamini, Giacomo; Ceroni, Paola; Lee, Lay-Theng; Schutz, Andri; Sakamoto, Junji; Zenobi, Renato; VandeVondele, Joost; Schluter, A. Dieter; J. Am. Chem. Soc. 2014, 136(16), 6103-6110, DOI: 10.1021/ja501849y ;Synthesis of Two-​Dimensional Analogues of Copolymers by Site-​to-​Site Transmetalation of Organometallic Monolayer Sheets
3) Hu, Chih-Wei; Sato, Takashi; Zhang, Jian; Moriyama, Satoshi; Higuchi, Masayoshi; ACS Appl. Mater. & Interfaces 2014, 6(12), 9118-9125, DOI: 10.1021/am5010859 ; Three-​Dimensional Fe(II)​-​based Metallo-​Supramolecular Polymers with Electrochromic Properties of Quick Switching, Large Contrast, and High Coloration Efficiency
4) Takada, Kenji; Sakamoto, Ryota; Yi, Shi-Ting; Katagiri, Shunsuke; Kambe, Tetsuya; Nishihara, Hiroshi; J. Am. Chem. Soc. 2015, 137(14), 4681-4689, DOI: 10.1021/ja510788b ; Electrochromic Bis(terpyridine)​metal Complex Nanosheets
5) Tsukamoto, Takamasa; Takada, Kenji; Sakamoto, Ryota; Matsuoka, Ryota; Toyoda, Ryojun; Maeda, Hiroaki; Yagi, Toshiki; Nishikawa, Michihiro; Shinjo, Naoaki; Amano, Shuntaro; Iokawa, Tadashi; Ishibashi, Narutaka; Oi, Tsugumi; Kanayama, Koshiro; Kinugawa, Rina; Koda, Yoichiro; Komura, Toshiyuki; Nakajima, Shuhei; Fukuyama, Ryota; Fuse, Nobuyuki; Mizui, Makoto; Miyasaki, Masashi; Yamashita, Yutaro; Yamada, Kuni; Zhang, Wenxuan; Han, Ruocheng; Liu, Wenyu; Tsubomura, Taro; Nishihara, Hiroshi; J. Am. Chem. Soc. 2017, 139(15), 5359-5366, DOI: 10.1021/jacs.6b12810 ; Coordination Nanosheets Based on Terpyridine-​Zinc(II) Complexes: As Photoactive Host Materials
1185464-11-2-CS014621.pdf 下载
1185464-11-2-CS014621-MS.pdf 下载

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4',4''''-(5'-(4-([2,2':6',2''-三吡啶]-4'-基)苯基)-[1,1':3',1''-三苯基]-4,4'-二基)二-2,2':6',2'''-三吡啶
4',4''''-(5'-(4-([2,2':6',2''-三吡啶]-4'-基)苯基)-[1,1':3',1''-三苯基]-4,4'-二基)二-2,2':6',2'''-三吡啶