MIL-88A(Fe)
MIL-88A(Fe)
CAS:1138446-56-6
分子式:C12H6O13Fe
分子量:414.01
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品牌 / 纯度 / 包装
材料名称：MIL-88A(Fe)
其他名称：NA
CAS：1138446-56-6
其他名称：NA
CAS：1138446-56-6
结构信息
| 单位分子式 | C12H6O13Fe3 | 单位分子量 | 525.70 | ||
| 配位金属 | Fe | 配体 | 富马酸（CAS：110-17-8） | ||
| 孔径 | 活化后<1nm, 未活化(溶剂撑满孔道状态下) 1.1-1.4nm | 孔容 | |||
| 比表面 | N2测BET基本无吸附 | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 红棕色粉末 |  |
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| 粒径 | 300nm*2um 纺锤状晶型颗粒 | |||
稳定性
1) MIL-88A(Fe) 在空气中稳定，在水溶液和酸性条件下较稳定
2) 高热稳定性、热分解温度大于250℃
2) 高热稳定性、热分解温度大于250℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前150度（真空）烘箱活化3小时
2) 建议使用前150度（真空）烘箱活化3小时
其他特性
荧光:NA
应用领域
1) 储气材料和吸附材料;具有特殊的“呼吸”效应
2) 作为路易斯酸催化剂
2) 作为路易斯酸催化剂
表征图谱
参考文献
1) C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Ferey. Science 2007, 315 (5820) , 1828-1831, DOI: 10.1126/science.1137975 ; Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks.
2）L. Wang, Y. Zhang, X. Li, Y. Xie, J. He, J. Yu, Y. Song, Sci Rep 2015, 5, 14341, DOI: 10.1038/srep14341 ; The MIL-88A-Derived Fe3O4-Carbon Hierarchical Nanocomposites for Electrochemical Sensing；
3）Ying Zhang, Jiabin Zhou, Xin Chen, Luo Wang, Weiquan Cai. Chemical Engineering Journal, 2019, DOI: 10.1016/j.cej.2019.03.108. Coupling of heterogeneous advanced oxidation processes and photocatalysis in efficient degradation of tetracycline hydrochloride by Fe-based MOFs: synergistic effect and degradation pathway.【文献解读】；
4）Ning Liu, Wenyuan Huang, Xiaodong Zhang, Liang Tang, Liang Wang, Yuxin Wang, Minghong Wu. Applied Catalysis B: Environmental, 2017; DOI: 10.1016/j.apcatb.2017.09.020. Ultrathin graphene oxide encapsulated in uniform MIL-88A(Fe) for enhanced visible light-driven photodegradation of RhB.【文献解读】;
5) Xiao-Hong Yi, Haodong Ji, Chong-Chen Wang, Yang Li, Yu-Hang Li, Chen Zhao, Ao Wang, Huifen Fu, Peng Wang, Xu Zhao, Wen Liu. Applied Catalysis B: Environmental, 2021; DOI: 10.1016/j.apcatb.2021.120229. Photocatalysis-activated SR-AOP over PDINH/MIL-88A(Fe) composites for boosted chloroquine phosphate degradation: performance, mechanism, pathway and DFT calculations.【文献解读】;
6) T. Chalati, P. Horcajada, R. Gref, P. Couvreur, C. Serre; Journal of Materials Chemistry, 2011, 21, 2220-2227; DOI: 10.1039/c0jm03563g; Optimisation of the synthesis of MOF nanoparticles made of flexible porous iron fumarate MIL-88A.【文献解读】;
7) Wen-Tao Xu, Lin Ma, Fei Ke, Fu-Min Peng, Geng-Sheng Xu, Yu-Hua Shen, Jun-Fa Zhu, Ling-Guang Qiu, Yu-Peng Yuan*; Dalton Transactions, 2014, 43, 3792-3798; DOI: 10.1039/c3dt52574k; Metal–organic frameworks MIL-88A hexagonal microrods as a new photocatalyst for efficient decolorization of methylene blue dye.【文献解读】
