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2',5'-dimethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid
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2',5'-dimethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid
2',5'-dimethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid
CAS:1119195-98-0 分子式:C24H18O8 分子量:434.39492
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产品名称:2',5'-dimethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid
其他名称:H4TPTC-Me
CAS:1119195-98-0
结构信息
分子式 C24H18O8 分子量 434.39492
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:NOTT-106 [r1]; Me-PCN-125 [r2]; Cu2TPTC-Me [r3]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) X. Lin , I. Telepeni , A. J. Blake , A. Dailly , C. M. Brown , J. M. Simmons , M. Zoppi , G. S. Walker , K. M. Thomas , T. J. Mays , P. Hubberstey , N. R. Champness and M. Schröder , J. Am. Chem. Soc., 2009, 131 , 2159-2171, DOI:10.1021/ja806624j ; High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites 
2) Park, J.; Wang, Z.; Sun, L.; Chen, Y.; Zhou, H.; J. Am. Chem. Soc. 2012, 134, 49, 20110-20116, DOI: 10.1021/ja3085884 ; Introduction of Functionalized Mesopores to Metal–Organic Frameworks via Metal–Ligand–Fragment Coassembly 
3) Xia, T.; Cai, J.; Wang, H.; Duan, X.; Cui, Y.; Yang, Y.; Qian, G.; Microporous  Mesoporous Mater. 2015, 215, 109-115, DOI: 10.1016/j.micromeso.2015.05.036

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2',5'-dimethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid
2',5'-dimethyl-[1,1':4',1''-terphenyl]-3,3'',5,5''-tetracarboxylic acid