UiO-66(Zr)
UiO-66
CAS:1072413-89-8
分子式:C48H28O32Zr6
分子量:1664.06
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材料名称：UIO-66
其他名称：UIO-66-BDC
CAS：1072413-89-8
其他名称：UIO-66-BDC
CAS：1072413-89-8
结构信息
| 单位分子式 | C48H24O32Zr6 | 单位分子量 | 1660.03 | ||
| 配位金属 | Zr | 配体 | 对苯二甲酸（CAS：100-21-0） | ||
| 孔径 | 0.8nm, 1.1nm | 孔容 | 0.5 cm3/g | ||
| 比表面 | BET比表面1000 m2/g ; 添加调节剂调节后BET可增加至1500-2000 m2/g | ||||
| 模拟结构 |   |
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产品性状
| 产品形貌 | 白色粉末 White Powder |
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| 粒径 | 200nm-1um | |||
稳定性
1) UIO-66 非常稳定，在水溶液和酸性条件下稳定。UIO-66是时间稳定性最好的MOF之一，可以长期稳定存放。
2) 高热稳定性、热分解温度大于400℃
2) 高热稳定性、热分解温度大于400℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 气体吸附实验前建议使用前120度（真空）脱气12小时
2) 气体吸附实验前建议使用前120度（真空）脱气12小时
其他特性
荧光:NA
应用领域
1) 储气材料和吸附材料
2) UIO-66的刚性结构是良好的催化剂载体
2) UIO-66的刚性结构是良好的催化剂载体
表征图谱
参考文献
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability【文献解读】
2) S. J. Garibaya, S. M. Cohen, Chem. Commun., 2010,46, 7700-7702, DOI: 10.1039/C0CC02990D ; Isoreticular synthesis and modification of frameworks with the UiO-66 topology
3) P.Yang, F. Mao, Y. Li, Q. Zhuang, J. Gu, Chem. Eur. J. 2018, 24, 2962-2970, DOI : 10.1002/chem.201705020 ; Hierarchical Porous Zr‐Based MOFs Synthesized by a Facile Monocarboxylic Acid Etching Strategy；
4）Loredana Valenzano, Bartolomeo Civalleri, Sachin Chavan, Silvia Bordiga, Merete H. Nilsen, Søren Jakobsen, Karl Petter Lillerud, Carlo Lamberti; Chemistry of Materials, 2011, 23, 42; DOI ：10.1021/cm1022882; Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory【文献解读】；
5) Greig C. Shearer, Sachin Chavan, Silvia Bordiga, Stian Svelle, Unni Olsbye, Karl Petter Lillerud*; Chemistry of Materials, 2016, 28, 3749−3761; DOI：10.1021/acs.chemmater.6b00602; Defect Engineering: Tuning the Porosity and Composition of the Metal−Organic Framework UiO-66 via Modulated Synthesis【文献解读】；
6）Frederik Vermoortele, Bart Bueken, Gaëlle Le Bars, Ben Van de Voorde, Matthias Vandichel, Kristof Houthoofd, Alexandre Vimont, Marco Daturi, Michel Waroquier, Veronique Van Speybroeck, Christine Kirschhock, Dirk E. De Vos; Journal of the American Chemical Society, 2013, 135, 11465-11468; DOI：10.1021/ja405078u; Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal−Organic Frameworks: The Unique Case of UiO-66(Zr) 【文献解读】;
7) Claudia Gomes Silva, Ignacio Luz, Francesc X. Labres i Xamena, Avelino Corma; CHEMISTRY A EUROPEAN JOURNAL, 2010, 16, 11133-11138; DOI：10.1002/chem.200903526; Water Stable Zr–Benzenedicarboxylate Metal–Organic Frameworks as Photocatalysts for Hydrogen Generation【文献解读】;
8) Jared B. DeCoste, Gregory W. Peterson, Himanshu Jasuja, T. Grant Glover, Yougui Huang, Krista S. Walton; Journal of Materials Chemistry A, 2013, 1, 5642-5650; DOI：10.1039/c3ta10662d; Stability and Degradation Mechanisms of Metal-Organic Frameworks containing the Zr₆O₄(OH)₄ Secondary Building Unit【文献解读】；
9）Gregory E. Cmarik, Min Kim, Seth M. Cohen, Krista S. Walton; Langmuir, 2012, 28, 15606-15613; DOI：10.1021/la3035352; Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization【文献解读】；
10) Shixiong Li, Shengli Sun, Haizhen Wu, Chaohai Wei, Yun Hu; Catalysis Science & Technology, 2018, 8, 1696-1703; DOI：10.1039/c7cy02622f; Effects of electron-donating groups on the photocatalytic reaction of MOFs 【文献解读】
