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N,N',N"-三-2-吡啶基胺
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N,N',N"-三-2-吡啶基胺
N,N-di-2-pyridinyl-2-Pyridinamine
CAS:10428-50-9 分子式:C15H12N4 分子量:248.28258
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产品名称:Tris(2-​pyridyl)​amine
其他名称:tripyam ; 2,​2',​2''-​tpa ; 2-TPA ; TPN ; tmpa;N,​N-​Di-​2-​pyridinyl-​2-​pyridinamine; 2,​2',​2''-​Tripyridylamine; NSC 176061; Tri-​2-​pyridylamine;
CAS:10428-50-9
结构信息
分子式 C15H12N4 分子量 248.28258
性状照片  
性质说明
1) 可溶于DMF、DMSO等
2) 室温密封保存
合成应用
1) 可作为配体用于合成MOF材料:RuCl2(py)​(tripyam) [r1]
表征图谱
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
参考文献
1) Mosny, Karoline K.; de Gala, Susan R.; Crabtree, Robert H.; Transition Metal Chemistry 1995, 20(6), 595-599, DOI: 10.1007/BF00136427 ; Arene ruthenium complexes of the thermally resistant ligand tri-​2-​pyridylamine
2) Yang, Wenyu; Schmider, Hartmut; Wu, Qingguo; Zhang, You-sheng; Wang, Suning; Inorg. Chem. 2000, 39(11), 2397-2404, DOI: 10.1021/ic991436m ; Syntheses, Structures, and Fluxionality of Blue Luminescent Zinc(II) Complexes: Zn(2,​2',​2''-​tpa)​Cl2, Zn(2,​2',​2''-​tpa)​2(O2CCF3)​2, and Zn(2,​2',​3''-​tpa)​4(O2CCF3)​2 (tpa = Tripyridylamine)
3) Perez, Julio; Morales, Dolores; Garcia-Escudero, Luis A.; Martinez-Garcia, Hector; Miguel, Daniel; Bernad, Pablo; Dalton Trans. 2009, (2), 375-382, DOI: 10.1039/B812604F ; Synthesis of new copper(I) complexes with tris(2-​pyridyl) ligands. Applications to carbene and nitrene transfer reactions
4) Jopp, Melanie; Becker, Jonathan; Becker, Sabine; Miska, Andreas; Gandin, Valentina; Marzano, Cristina; Schindler, Siegfried; Euro. J. Med. Chem. 2017, 132, 274-281, DOI: 10.1016/j.ejmech.2017.03.019 ; Anticancer activity of a series of copper(II) complexes with tripodal ligands

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N,N',N"-三-2-吡啶基胺
N,N',N"-三-2-吡啶基胺